T³: Adventures in UV LEDs, photoinitiators and gel nail polish

Several weeks ago we launched, with little fanfare, a new blog post series we’re calling “Tech Talk Tuesday,” or T³. Each Tuesday, Shawn, Sarah and Nick will take control of the blog and talk about…whatever they want, really. From projects, to current events, to teardowns, to electronics concepts, we’ve given them free rein to discuss the stuff in their endlessly engineering minds. If you have suggestions for a topic you’d like to see them cover, let them know in the comments!


I am a nail polish enthusiast. It started off as a way to cover my nails so that I stopped biting them, but it turned into a way to express my nerdy-ness in a cool and artistic way (that also stopped me from biting my nails).

Some nerdy nails of my past

One of the new fads in nail polish is “gel” or “shellac” polish. These nail polishes differ in that they are cured, by UV light, into a plastic on your nails that supposedly lasts longer and doesn’t chip. For a while they weren’t selling the nail polish itself, and you would have to go to a salon to get this done. I never did, because that’s no fun, and I can’t tell a manicurist to put Kirby faces on my nails.

So I waited. And sure enough these gel/shellac/lacquer polishes were available to buy. Cool, I wanted to try them. Problem was, they were selling the accompanying lamps for around $45. As an electrical engineer, that seems ridiculous to me. So I grabbed some UV LEDs from our stock, and I started testing.

Make-shift UV LED lamp

A short lesson in light: Visible light (what we see as things like red, green, blue and so on) is categorized by different wavelengths. For example, what we see as green light is about 495-570 nm on the Electromagnetic Spectrum. All visible light ranges from about 400 nm (violet) to about 780 nm (red).

Visable Light table

Pretty

Ultra Violet light (UV light) ranges from about 100 nm to 400 nm. As you can see in this graph, there are three main types of UV light: A, B and C.

Light Spectrum graph

All LEDs emit a little bit of UV light, but they don’t usually emit infrared light. This is why they don’t get hot like incandescent light bulbs, which emit a very wide range of light, including infrared and UV. There are special UV LEDs that emit more UV light, but it’s still only UV-A, and concentrated around 400 nm as seen on this graph:

Graph of typical UV LED light distrabution

Gel nail polish uses photoinitiators that, once exposed to the right wavelength of light, will absorb that energy and activate other molecules that form the reaction, turning the wet nail polish into a hard, plastic-like substance. The problem is that there are a lot of photoinitiators, and nail polish manufactures try to use photoinitiators that perfectly match the UV lamps that they sell. Seeing as UV LEDs aren’t the only UV light-emitting tools, manufacturers have a lot of UV wavelength to work with. This is why I thought my little makeshift UV LED “lamp” might not work. While looking into other types of UV nail polish lamps, I noticed the use of UV compact fluorescent light bulbs (CFLs). These also only really emit in the UV-A spectrum, but they are more concentrated around 375 nm, though it is more distributed:

Graph of typical UV CFL light distrabution

I was curious if a 25 nm difference was large enough that the nail polish wouldn’t cure. Most gel nail polishes I saw had options for either UV LEDs or bulbs, and only the time to cure differed. I was pretty confident at this point that, regardless of the manufacturer, my “lamp” could cure the gel nail polish, even though it may take longer (say, a minute, as opposed to the 30 seconds it says it takes on the bottle).

Just to be safe, the first nail polish I tested specifically said UV LED-cured, and was an all-in-one application (base coat, color and top coat) so I didn’t have to mess around with multiple coats.

The result? Awesome!

Black nail polish UV LED cured

All the good things they say about gel nail polish are true. It has relatively little scent, unlike normal nail polish. It took about a minute and a half to cure instead of 30 seconds with my “lamp,” but that’s still super fast compared to regular nail polish. My first tester lasted about two weeks before it started chipping and peeling, which was amazing.

My one complaint about it is that it’s harder to get off (which is what it’s made for). If you don’t want to peel it off your fingers (which I do not suggest, as it took a small layer of my nail with it), you have to soak it off in a special alcohol mixture that I wouldn’t say was fun for my cuticles.

Once I had experienced my first success with what I knew was probably going to work, I wanted to venture out and test more types. I was worried about different colors because they would need to use different photoinitiators, since some are slightly colored (usually yellow-ish). With a dark color like black I knew it would be easy, because they could use whatever photoinitiators work best since you wouldn’t really see it in the dark color. More specific lighter colors would take more specific photoinitiators, and could change what wavelength it needed.

Colored nail polish UV LED cured

The instructions on these suggested using a base and top coat also, but I just put them on straight. They left a tacky layer once cured that you just wipe off with a cotton ball and some alcohol, but it made it hard for me to know when they were actually done curing. I cured them for about two minutes (could have been too long; I don’t know because of the tacky layer). The lighter ones did take longer, and they weren’t shiny because that is what a top coat is for. But I like it; it worked all the same. These didn’t last as long, but I am assuming that is why they suggest a base coat.

My final thoughts:

Gel nail polish is pretty cool. It takes care of all the things I didn’t like about regular nail polish, like the bad smell, the length of time it takes to dry and the fact that it wouldn’t even last a week on my nails, especially when I worked hard to make them super awesome.

My UV LED lamp worked! It took longer to cure than it said it should on the nail polish bottle, but it was still way faster than normal nail polish. I am fine with it taking a minute or two longer since it is a fraction of the price to do myself than to buy a lamp or go to a salon. Even if I were to buy a lamp, it still wouldn’t work the same way for every different manufacturer’s polish.

Another cool thing about gel nail polish is that since you cure each layer separately, you can wipe off a new layer before you cure it without messing up the layer underneath. This makes my nail art way easier, and opens up cool new things that I may not have been able to do before. Extra nerdy gel nails, here I come!

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